Sorbitan Monooleate (Span 80) – E494 W/O Emulsifier & Lubricant

Overview

  • Chemical Nature
    Non-ionic surfactant derived from the esterification of sorbitol with oleic acid.
  • Appearance & Specs
    Pale yellow to amber oily liquid  |  HLB Value: ~4.3
  • Primary Application (Emulsification)
    W/O Emulsion Specialist. Especially effective at stabilizing water-in-oil emulsions. Provides texture control and stability in fat-rich formulations.
  • Additional Roles
    Functions as a dispersant and lubricant in various industrial applications.
  • Key Functions
    W/O Emulsifier & Lubricant.

Molecular Structure

  • Structural Components
    Hydrophilic Core: Sorbitan (anhydrosorbitol) ring structure.
    Hydrophobic Moiety: Single oleic acid molecule esterified to the core.
  • Mechanism of Action
    Fluidity & Lipophilicity. The long oleic acid chain imparts fluidity and strong compatibility with lipid phases. While it has some hydrophilic balance, it is predominantly lipophilic, making it insoluble in water but ideal for dispersing in oils and stabilizing W/O emulsions.

Specifications:

Before delving into technical details, it’s important to note that Sorbitan Monooleate does more than just emulsify: it enhances the physical characteristics of food systems by improving texture, dispersibility, and stability. It helps regulate fat distribution, reduces graininess, and ensures consistent product quality.
Key qualitative attributes include:
  • Amber to pale yellow oily liquid form
  • Minimal characteristic odor
  • Insoluble in water; dispersible and compatible with lipid systems
  • Stable under normal processing and storage conditions
  • Works synergistically with stronger hydrophilic surfactants (e.g., polysorbates) to tailor custom HLB systems
Test ItemUnitMinimum ValueMaximum Value
HLB value——4.3
Saponification ValuemgKOH/g145160
Iodine ValuemgKOH/g193210
Acid ValuemgKOH/g8
Moisture%2
Fatty Acidsw%7377
Polyolw%2832
Phosphorusmg/kg3
Leadmg/kg2

Applications:

  • Textile & Fiber: Acts as a smoothing lubricant and antistatic agent for synthetic fibers, preventing breakage during high-speed spinning.
  • Industrial Explosives: The primary emulsifier used to stabilize emulsion explosives (matrix), allowing for safe storage and transport.
  • Cosmetics: Used in “rich” night creams and ointments to create Water-in-Oil emulsions that provide a protective barrier on the skin.
  • Food Processing: Functions as a defoamer in yeast production and sugar refining, and as a dispersant for oil-soluble colors.
Superior W/O Emulsification

With a low HLB of 4.3, Span 80 is the ideal choice for creating stable Water-in-Oil emulsions, where water droplets are suspended within a continuous oil phase.

High Lubricity (Oleic Source)

Derived from unsaturated Oleic Acid, it offers excellent surface lubrication properties, making it essential for reducing friction in textile manufacturing and metalworking.

The Perfect Tween 80 Partner

Span 80 and Tween 80 are the industry’s most common ‘power couple.’ Mixing them allows formulators to hit any specific HLB target between 4.3 and 15.0 for customized stability.

Liquid Handling

Unlike Span 40 or 60 (which are solids), Span 80 is a liquid at room temperature, making it easy to pump, pour, and mix into cold-process formulations without heating.

Smooth textile fibers running through machinery, demonstrating the antistatic and lubricating properties of Sorbitan Monooleate (Span 80).
Blending Span 80 and Tween 80 surfactants in a lab to achieve optimal Hydrophile-Lipophile Balance.

storage & package:

Storage:
Store in a cool, dry, and well-ventilated area, away from direct sunlight and sources of heat.
Avoid contact with harmful or incompatible substances. Handle with care during transportation to prevent leakage or contamination.

Transportation:
Transport as a general chemical product, following standard safety and handling procedures.

Package:
Sorbitan Monooleate is packed in high-quality PE drums with double-seal lids.
Standard packaging sizes include 25kg/drum, 200kg/drum, and 1000kg IBC tote to meet different usage needs.

25 Kg /drum
200kg/drum
1000kg IBC

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